Understanding of zeolite acidity based on a method of ammonia temperature programmed desorption (TPD) experiment: step by step improvements

  报告时间2015921日(星期一)13:30 

  报告地点:能源1号楼楼会议室 

  报告人Prof. Miki Niwa, Nagoya Industrial Science Research Institute, Japan 

  报告摘要 

  His historical overview of the development of ammonia TPD experiment to measure the solid acidity of zeolite is reviewed. Ammonia TPD is controlled by the equilibrium between ammonia molecules in the gas phase and on the surface. The method to measure number and strength of the acid sites of zeolite is precisely explained. In order to overcome the drawback of the method, IRMS-TPD in which not only mass spec but also IR is working together to get the information of the structure of acid site is proposed. We have very detailed information of the acid sites of zeolite using this method. In addition, DFT calculation supports the experimental observations.     

  报告人简介 

  Miki Niwa was born in March 1946 in Aichi, Japan. He received his B. S., M. S., and Ph. D. degrees in applied and synthetic chemistry, from Nagoya University, working with Professor Yuichi Murakami. After studying in Nagoya University as assistant professor and lecturer, he was appointed a professor of Tottori University in 1992. He retired in 2011, and now is working as senior researcher of Nagoya Industrial Science Research Institute, guest professor of Aichi Institute of Technology, visiting professor of National University of Singapore. He has received the Catalysis Society of Japan Award for 2003 and the Japan Petroleum Institute Award for 2007.  His research interest is mainly on the catalyst and catalysis of zeolites and metal oxides.    

  报告联系人DNL1208  贺莎莎 (89870) 

版权所有 © 中国科学院大连化学物理研究所 本站内容如涉及知识产权问题请联系我们 备案号:辽ICP备05000861号-1 辽公网安备21020402000367号